By train

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Empoli railway station has a large user base, as it is an important railway hub, served by two lines: Florence - Pisa and Empoli - Siena.
You can get to Empoli in just 30 minutes from Florence and in 40 minutes from Pisa, with a frequency of about three trains every hour.
You can get to Empoli in an hour from Siena and in 50 minutes from Livorno.

Take a look at the train timetables.